Wu, JuanjuanSu, DongdongQin, CaiqinLi, WeiRodrigues, JoãoSheng, RuilongZeng, Lintao2022-03-082022-03-082019Wu, J., Su, D., Qin, C., Li, W., Rodrigues, J., Sheng, R., & Zeng, L. (2019). A fast responsive chromogenic and near-infrared fluorescence lighting-up probe for visual detection of toxic thiophenol in environmental water and living cells. Talanta, 201, 111-118. https://doi.org/10.1016/j.talanta.2019.03.113http://hdl.handle.net/10400.13/4125Thiophenols as high toxic environmental pollutants are poisonous for animals and aquatic organisms. Therefore, it is indispensable to monitor thiophenols in the environment. Herein, a novel near-infrared fluorescent probe was developed for the detection of thiophenols, which was easily prepared by one-step coupling of 2,4-dini trobenzenesulfonyl chloride with Nile blue. The probe showed a significant near infrared (∼675 nm) fluores cence “turn-on” response to thiophenols with some good features including chromogenic reaction, high sensi tivity and selectivity, fast response, near-infrared emission along with low detection limit (1.8 nM). The probe was employed to rapidly and visually determine thiophenols in several industrial wastewaters with good re coveries (90–110%). Moreover, this probe has been demonstrated good capability for imaging thiophenol in HeLa cellsengNile blueNear-infraredFluorescent probeThiophenolsChromogenicImaging.Faculdade de Ciências Exatas e da EngenhariaCentro de Química da MadeiraA fast responsive chromogenic and near-infrared fluorescence lighting-up probe for visual detection of toxic thiophenol in environmental water and living cellsjournal article10.1016/j.talanta.2019.03.113