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Assessment of the changes in the cellulosic surface of micro and nano banana fibres due to saponin treatment

dc.contributor.authorCordeiro, Nereida
dc.contributor.authorFaria, Marisa
dc.contributor.authorAbraham, Eldho
dc.contributor.authorPothan, Laly A.
dc.date.accessioned2021-05-03T11:00:13Z
dc.date.available2021-05-03T11:00:13Z
dc.date.issued2013
dc.description.abstractThe effect of saponin on the surface properties of banana fibres was studied by Inverse Gas Chromatography (IGC). Parameters including the dispersive component of the surface energy, surface heterogeneity, surface area, as well as acid-base surface properties were determined for saponin modified banana micro and nanofibres. These parameters show a more extensive saponin coating on the nanofibres with a network formation which is explained by the higher reactivity of nanofibres due to the higher surface energy, specific interaction and higher surface area presented by the nanofibres. The energetic profile indicates that both micro and nanofibres coated with saponin interact with the same, or similar, energy active sites. Saponin treatment reduces considerably the surface area of the fibres, with the consequent decrease in the monolayer capacity. The interaction with the polar probes clearly indicates that saponin treatment creates new polar active sites for specific interactions in both samples. However, the treatment increases predominately the basicity of the fibre surface with more relevance to the nanofibres. This behaviour will lead to better polymer/fibre interaction during composite preparation.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationCordeiro, N., Faria, M., Abraham, E., & Pothan, L. A. (2013). Assessment of the changes in the cellulosic surface of micro and nano banana fibres due to saponin treatment. Carbohydrate polymers, 98(1), 1065-1071.pt_PT
dc.identifier.doi10.1016/j.carbpol.2013.07.002pt_PT
dc.identifier.urihttp://hdl.handle.net/10400.13/3344
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherElsevierpt_PT
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt_PT
dc.subjectSaponin treatmentpt_PT
dc.subjectSurface propertiespt_PT
dc.subjectCelulosept_PT
dc.subjectBanana fibrespt_PT
dc.subjectInverse Gas Chromatographypt_PT
dc.subject.pt_PT
dc.subjectFaculdade de Ciências Exatas e da Engenhariapt_PT
dc.titleAssessment of the changes in the cellulosic surface of micro and nano banana fibres due to saponin treatmentpt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage1071pt_PT
oaire.citation.issue1pt_PT
oaire.citation.startPage1065pt_PT
oaire.citation.titleCarbohydrate Polymerspt_PT
oaire.citation.volume98pt_PT
person.familyNamecordeiro
person.familyNameFaria
person.givenNamenereida
person.givenNameMarisa Camacho Gonçalves
person.identifier1612636
person.identifier.ciencia-id521A-0F62-EA39
person.identifier.ciencia-idD716-6F48-AD0E
person.identifier.orcid0000-0001-6006-3415
person.identifier.orcid0000-0002-9158-6961
person.identifier.ridO-2253-2019
person.identifier.scopus-author-id7004319456
rcaap.rightsopenAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublication3d02b657-c48c-4f56-813a-1284b81960f3
relation.isAuthorOfPublication57ef72f0-8e40-4853-b4ab-416884e127fa
relation.isAuthorOfPublication.latestForDiscovery3d02b657-c48c-4f56-813a-1284b81960f3

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