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Synthesis of onion‐peel nanodendritic structures with sequential functional phosphorus diversity

2015Journal article Open access
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dc.contributor.authorKatir, Nadia
dc.contributor.authorEl Brahmi, Nabil
dc.contributor.authorEl Kadib, Abdelkrim
dc.contributor.authorMignani, Serge
dc.contributor.authorCaminade, Anne‐Marie
dc.contributor.authorBousmina, Mosto
dc.contributor.authorMajoral, Jean Pierre
dc.date.accessioned2024-02-28T09:40:48Z
dc.date.available2024-02-28T09:40:48Z
dc.date.issued2015
dc.description.abstractThe preparation of novel families of phosphorus based macromolecular architectures called “onion peel” phosphorus nanodendritic systems is reported. This con struct is based on the versatility of methods of synthesis using several building blocks and on the capability of these systems to undergo regioselective reactions within the cas cade structure. Sustainable metal-free routes such as the Staudinger reaction or Schiff-base condensation, involving only water and nitrogen as byproducts, allow access to sev eral dendritic macromolecules bearing up to seven different phosphorus units in their backbone, each of them featuring specific reactivity. The presence of the highly aurophilic P= N¢P=S fragment enables selective ligation of Au I within the dendritic framework.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationKatir, N., El Brahmi, N., El Kadib, A., Mignani, S., Caminade, A. M., Bousmina, M., & Majoral, J. P. (2015). Synthesis of onion‐peel nanodendritic structures with sequential functional phosphorus diversity. Chemistry–A European Journal, 21(17), 6400-6408.pt_PT
dc.identifier.doi10.1002/chem.201500138pt_PT
dc.identifier.urihttp://hdl.handle.net/10400.13/5587
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherWileypt_PT
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/pt_PT
dc.subjectDendrimerspt_PT
dc.subjectGoldpt_PT
dc.subjectNanostructurespt_PT
dc.subjectPhosphoruspt_PT
dc.subjectViologenspt_PT
dc.subject.pt_PT
dc.subjectFaculdade de Ciências Exatas e da Engenhariapt_PT
dc.titleSynthesis of onion‐peel nanodendritic structures with sequential functional phosphorus diversitypt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage6408pt_PT
oaire.citation.issue17pt_PT
oaire.citation.startPage6400pt_PT
oaire.citation.titleChemistry – A European Journalpt_PT
oaire.citation.volume21pt_PT
person.familyNameMignani
person.familyNameMajoral
person.givenNameSerge
person.givenNameJean Pierre
person.identifier.ciencia-id8018-B5D2-6983
person.identifier.orcid0000-0002-1383-5256
person.identifier.orcid0000-0002-0971-817X
person.identifier.scopus-author-id7003374430
rcaap.rightsopenAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublicationcabd0aa0-5827-4e97-889b-922136d2dd4b
relation.isAuthorOfPublication88a48eea-f909-4dc3-88b3-e0deeea5a65d
relation.isAuthorOfPublication.latestForDiscoverycabd0aa0-5827-4e97-889b-922136d2dd4b

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