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A convenient route for the preparation of the monohydride catalyst trans-[RuCl(H)(dppe)2] (dppe=Ph2PCH2CH2PPh2): improved synthesis and crystal structure

2013Journal article Restricted access
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dc.contributor.authorFigueira, João
dc.contributor.authorJardim, Manuel G.
dc.contributor.authorRodrigues, João
dc.contributor.authorValkonen, Arto
dc.contributor.authorRissanen, Kari
dc.date.accessioned2019-06-21T10:47:09Z
dc.date.available2019-06-21T10:47:09Z
dc.date.issued2013
dc.description.abstractA novel and improved room temperature synthesis of the monohydride catalyst trans-[RuCl(H)(dppe)2] complex (1, dppe (1,2-bis(diphenylphosphino)ethane) = Ph2PCH2CH2PPh2) proceeds through oxidation of methanol (the solvent) by the pentacoordinated cis-[RuCl(dppe)2][PF6] complex and t-BuOK as the base is described. Compound 1 was fully characterized by NMR (1H, 13C, 31P), ESI-MS(TOF +), FTIR and elemental analysis. The X-ray structure of 1 was reported for the first time and unambiguously confirms the trans-configuration of the complex.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationFigueira, J., Jardim, M. G., Rodrigues, J., Valkonen, A., & Rissanen, K. (2013). A convenient route for the preparation of the monohydride catalyst trans-[RuCl (H)(dppe) 2](dppe= Ph2PCH2CH2PPh2): Improved synthesis and crystal structure. Inorganic Chemistry Communications, 29, 123-127.pt_PT
dc.identifier.doi10.1016/j.inoche.2013.01.002pt_PT
dc.identifier.issn1387-7003
dc.identifier.urihttp://hdl.handle.net/10400.13/2415
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherElsevierpt_PT
dc.relationStrategic Project - UI 674 - 2011-2012
dc.subjectRutheniumpt_PT
dc.subjectHydrogenationpt_PT
dc.subjectHomogeneous catalisyspt_PT
dc.subjectHydridespt_PT
dc.subjectSyntethic methdospt_PT
dc.subjectX-ray crystal structurept_PT
dc.subject.pt_PT
dc.subjectFaculdade de Ciências Exatas e da Engenhariapt_PT
dc.subjectCentro de Química da Madeira
dc.titleA convenient route for the preparation of the monohydride catalyst trans-[RuCl(H)(dppe)2] (dppe=Ph2PCH2CH2PPh2): improved synthesis and crystal structurept_PT
dc.typejournal article
dspace.entity.typePublication
oaire.awardTitleStrategic Project - UI 674 - 2011-2012
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/3599-PPCDT/PTDC%2FQUI%2F64202%2F2006/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/3599-PPCDT/PTDC%2FCTM%2F098451%2F2008/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBD%2F29325%2F2006/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBD%2F65036%2F2009/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/PEst-OE%2FQUI%2FUI0674%2F2011/PT
oaire.citation.endPage127pt_PT
oaire.citation.startPage123pt_PT
oaire.citation.titleInorganic Chemistry Communicationspt_PT
oaire.citation.volume29pt_PT
oaire.fundingStream3599-PPCDT
oaire.fundingStream3599-PPCDT
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oaire.fundingStreamSFRH
oaire.fundingStream6817 - DCRRNI ID
person.familyNameFigueira
person.familyNameRodrigues
person.familyNameValkonen
person.familyNameRissanen
person.givenNameJoão
person.givenNameJoão
person.givenNameArto
person.givenNameKari
person.identifier.ciencia-idA81C-620E-DD6A
person.identifier.orcid0000-0001-8819-2278
person.identifier.orcid0000-0003-4552-1953
person.identifier.orcid0000-0003-2806-3807
person.identifier.orcid0000-0002-7282-8419
person.identifier.ridB-6816-2008
person.identifier.ridH-8064-2013
person.identifier.scopus-author-id9233278800
project.funder.identifierhttp://doi.org/10.13039/501100001871
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project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsrestrictedAccesspt_PT
rcaap.typearticlept_PT
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