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Untargeted fingerprinting of cider volatiles from different geographical regions by HS-SPME/GC-MS

dc.contributor.authorPerestrelo, Rosa
dc.contributor.authorSilva, Catarina L.
dc.contributor.authorSilva, Pedro
dc.contributor.authorMedina, Sonia
dc.contributor.authorPereira, Regina
dc.contributor.authorCâmara, José S.
dc.date.accessioned2022-10-03T15:05:59Z
dc.date.available2022-10-03T15:05:59Z
dc.date.issued2019
dc.description.abstractThe volatomic fingerprint of ciders produced in different geographical regions from Madeira Island was estab lished using headspace solid phase microextraction combined with gas chromatography mass spectrometry (HS SPME/GC–MS) in order to explore the effects of geographical region on the volatile pattern ciders in addition to identify potential molecular geographic markers. A total of 107 volatile organic compounds (VOCs) belonging to different chemical families were identified from which 50 VOCs are common to all ciders analysed. Significant differences in the relative content of VOCs from ciders of different geographical regions were observed. The potential of the identified VOCs for ciders discrimination according to region was assessed through chemometric tools, such as principal components analysis (PCA) and partial least squares-discriminant analysis (PLS-DA). The PCA showed significant differences among ciders from different island geographical regions. Fifteen VOCs re sponsible for ciders discrimination were identified by PLS-DA. Fifteen VOCs, namely five terpenoids, four al cohols, three acids and three esters, present variable importance in projection (VIP) values higher than one. Our findings provide relevant information related to volatile signature of ciders produced in Madeira Island, which may be a useful tool to cider-making process contributing to improve the quality of the final product. In addition, the geographical discrimination recognizes the unique and distinctive characteristics that will allow in the future to protect the quality and typicity of products originating in certain geographical regions.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationPerestrelo, R., Silva, C. L., Silva, P., Medina, S., Pereira, R., & Camara, J. S. (2019). Untargeted fingerprinting of cider volatiles from different geographical regions by HS-SPME/GC-MS. Microchemical Journal, 148, 643-651.pt_PT
dc.identifier.doi10.1016/j.microc.2019.05.028pt_PT
dc.identifier.urihttp://hdl.handle.net/10400.13/4682
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherElsevierpt_PT
dc.relationStrategic Project - UI 674 - 2014
dc.relationNon-invasive, innovative and promising strategy for early diagnosis of breast cancer through the establishment of urinary volatile metabolomic profiles of breast cancer patients as well as from breast cancer tissues and breast cancer cell lines
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/pt_PT
dc.subjectVolatomic signaturept_PT
dc.subjectCiderpt_PT
dc.subjectGeographical regionpt_PT
dc.subjectHS-SPMEpt_PT
dc.subjectGC–MSpt_PT
dc.subjectChemometricspt_PT
dc.subject.pt_PT
dc.subjectFaculdade de Ciências Exatas e da Engenhariapt_PT
dc.subjectCentro de Química da Madeira
dc.titleUntargeted fingerprinting of cider volatiles from different geographical regions by HS-SPME/GC-MSpt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.awardTitleStrategic Project - UI 674 - 2014
oaire.awardTitleNon-invasive, innovative and promising strategy for early diagnosis of breast cancer through the establishment of urinary volatile metabolomic profiles of breast cancer patients as well as from breast cancer tissues and breast cancer cell lines
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/PEst-OE%2FQUI%2FUI0674%2F2014/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/OE/SFRH%2FBD%2F97039%2F2013/PT
oaire.citation.endPage651pt_PT
oaire.citation.startPage643pt_PT
oaire.citation.titleMicrochemical Journalpt_PT
oaire.citation.volume148pt_PT
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStreamOE
person.familyNamePerestrelo
person.familyNameSousa Luís
person.familyNameSilva
person.familyNameMedina
person.familyNameCâmara
person.givenNameRosa
person.givenNameCatarina Grace
person.givenNamePedro
person.givenNameSonia
person.givenNameJosé
person.identifier1441319
person.identifierC-1300-2019
person.identifierG-3003-2013
person.identifier.ciencia-id251A-D5F7-9E32
person.identifier.ciencia-id9813-3B88-BA8D
person.identifier.ciencia-id481C-08CE-90E5
person.identifier.orcid0000-0002-7223-1022
person.identifier.orcid0000-0002-3018-3165
person.identifier.orcid0000-0001-7932-1015
person.identifier.orcid0000-0002-7231-6480
person.identifier.orcid0000-0003-1965-3151
person.identifier.ridI-2307-2014
person.identifier.ridM-2479-2014
person.identifier.scopus-author-id16686828800
person.identifier.scopus-author-id57194492726
person.identifier.scopus-author-id57203612189
person.identifier.scopus-author-id10140393000
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsopenAccesspt_PT
rcaap.typearticlept_PT
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