Publication
The organosolv fractionation of cork components
| dc.contributor.author | Cordeiro, Nereid | |
| dc.contributor.author | Neto, Carlos Pascoal | |
| dc.contributor.author | Rocha, Joao | |
| dc.contributor.author | Belgacem, Mohamed N. | |
| dc.contributor.author | Gandini, Alessandro | |
| dc.date.accessioned | 2021-05-05T13:16:31Z | |
| dc.date.available | 2021-05-05T13:16:31Z | |
| dc.date.issued | 2002 | |
| dc.description.abstract | Extractive-free cork from Quercus suber L. was submitted to organosolv fractionation and the effects of different process variables, such as ethanol/water ratio, temperature, time and the presence of acidic or alkaline catalysts, were studied. The variation of the relative proportions of extracted components, as a function of the processing conditions, could thus be established. Whereas the addition of 0.1 M acetic acid only increased the yield of extracted materials from about 15 to 23%, the use of sodium hydroxide, at the same concentration, produced a jump to 76%. In the case of the alkaline organosolv fractiona tion, an increase in process temperature, time and catalyst concentration led to an increase in the extraction yield, although in some cases this increase did not follow a sustained trend, as in the case of reaction time. Increasing the ethanol/water ratio led to a higher selectivity in favour of suberin extraction. Residual cork from different organosolv processes was characterised by FTIR and 13C solid-state NMR. The latter technique provided some valuable information about both process selectivity and cork morphology, particularly with respect to the positioning of suberin macromolecules in the cell wall. | pt_PT |
| dc.description.version | info:eu-repo/semantics/publishedVersion | pt_PT |
| dc.identifier.citation | Cordeiro, N., Neto, C. P., Rocha, J., Belgacem, M. N., & Gandini, A. (2002). The organosolv fractionation of cork components. Holzforschung, 56(2), 135-142. | pt_PT |
| dc.identifier.doi | 10.1515/HF.2002.023 | pt_PT |
| dc.identifier.uri | http://hdl.handle.net/10400.13/3366 | |
| dc.language.iso | eng | pt_PT |
| dc.peerreviewed | yes | pt_PT |
| dc.publisher | De Gruyter | pt_PT |
| dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | pt_PT |
| dc.subject | Cork | pt_PT |
| dc.subject | Quercus suber L. | pt_PT |
| dc.subject | Organosolv fractionation | pt_PT |
| dc.subject | Ethanol/water extraction | pt_PT |
| dc.subject | Suberin | pt_PT |
| dc.subject | FTIR | pt_PT |
| dc.subject | 13C NMR | pt_PT |
| dc.subject | . | pt_PT |
| dc.subject | Faculdade de Ciências Exatas e da Engenharia | pt_PT |
| dc.title | The organosolv fractionation of cork components | pt_PT |
| dc.type | journal article | |
| dspace.entity.type | Publication | |
| oaire.citation.endPage | 142 | pt_PT |
| oaire.citation.issue | 2 | pt_PT |
| oaire.citation.startPage | 135 | pt_PT |
| oaire.citation.title | Holzforschung | pt_PT |
| oaire.citation.volume | 56 | pt_PT |
| person.familyName | cordeiro | |
| person.givenName | nereida | |
| person.identifier | 1612636 | |
| person.identifier.ciencia-id | 521A-0F62-EA39 | |
| person.identifier.orcid | 0000-0001-6006-3415 | |
| person.identifier.rid | O-2253-2019 | |
| person.identifier.scopus-author-id | 7004319456 | |
| rcaap.rights | openAccess | pt_PT |
| rcaap.type | article | pt_PT |
| relation.isAuthorOfPublication | 3d02b657-c48c-4f56-813a-1284b81960f3 | |
| relation.isAuthorOfPublication.latestForDiscovery | 3d02b657-c48c-4f56-813a-1284b81960f3 |
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