Semiphenomenological model for gas-liquid phase transitions

Benilov, E. S.; Benilov, M. S.

http://hdl.handle.net/10400.13/4558

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Authors

Benilov, E. S.

Benilov, M. S.

Abstract(s)

We examine a rarefied gas with inter-molecular attraction. It is argued that the attraction force amplifies random density fluctuations by pulling molecules from lower-density regions into high-density regions and thus may give rise to an instability. To describe this effect, we use a kinetic equation where the attraction force is taken into account in a way similar to how electromagnetic forces in plasma are treated in the Vlasov model. It is demonstrated that the instability occurs when the temperature T is lower than a certain threshold value Ts depending on the gas density. It is further shown that, even if T is only marginally lower than Ts, the instability generates clusters with density much higher than that of the gas. These results suggest that the instability should be interpreted as a gas-liquid phase transition, with Ts being the temperature of saturated vapor and the high-density clusters representing liquid droplets.

Keywords

Gas-liquid phase transitions Semiphenomenological model . Faculdade de Ciências Exatas e da Engenharia

URI

http://hdl.handle.net/10400.13/4558

Citation

Benilov, E. S., & Benilov, M. S. (2016). Semiphenomenological model for gas-liquid phase transitions. Physical Review E, 93(3), 032148. 10.1103/PhysRevE.93.032148