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Advisor(s)
Abstract(s)
The lifetime of tungsten cathodes used in plasma spray torches is limited by processes leading
to a loss of cathode material. It was reported in the literature that the mechanism of their erosion
is the evaporation. A model of the ionization layer of a cathode is developed to study the
diffusive transport of evaporated tungsten atoms and tungsten ions produced due to ionization
by electron impact in a background argon plasma. It is shown that the Stefan–Maxwell
equations do not reduce to Fick law as one could expect for the transport of diluted species,
which is due to significant diffusion velocities of argon ions. The ionization of tungsten atoms
occurs in a distance of a few micrometers from the cathode surface and leads to a strong sink,
which increases the net flux of tungsten atoms far beyond that obtained in absence of tungsten
ions. This shows that the tungsten ions are driven by the electric field towards the cathode
resulting in no net diffusive flux and no removal of tungsten species from the ionization layer
even if convection is accounted for. A possible mechanism of removal is found by extending the
model to comprise an anode. The extended model resolves the inter-electrode region and
provides the plasma parameters for a current density corresponding to the value at the center of
the cathode under typical arc currents of 600 A and 800 A. The presence of the anode causes a
reversal of the electric field on the anode side, which pulls the ions away from the ionization
layer of the cathode. The net flux of tungsten ions can be further fortified by convection. This
model allows one to evaluate the loss of cathode material under realistic operating conditions in
a quantitative agreement with measured values.
Description
Keywords
Plasma spray torch Erosion Tungsten cathode Ionization layer Evaporation Field reversal Convection . Faculdade de Ciências Exatas e da Engenharia
Citation
Baeva, M., Benilov, M. S., Zhu, T., Testrich, H., Kewitz, T., & Foest, R. (2022). Modelling and experimental evidence of the cathode erosion in a plasma spray torch. Journal of Physics D: Applied Physics, 55(36), 365202.
Publisher
IOP Publishing